Artificial Intelligence (AI) systems are becoming increasingly powerful and autonomous, and may progress to surpass human intelligence levels, namely Artificial Superintelligence (ASI). During the progression from AI to ASI, it may exceed human control, violate human values, and even lead to irreversible catastrophic consequences in extreme cases. This gives rise to a pressing issue that needs to be addressed: superalignment, ensuring that AI systems much smarter than humans, remain aligned with human (compatible) intentions and values. Existing scalable oversight and weak-to-strong generalization methods may prove substantially infeasible and inadequate when facing ASI. We must explore safer and more pluralistic frameworks and approaches for superalignment. In this paper, we redefine superalignment as the human-AI co-alignment towards a sustainable symbiotic society, and highlight a framework that integrates external oversight and intrinsic proactive alignment. External oversight superalignment should be grounded in human-centered ultimate decision, supplemented by interpretable automated evaluation and correction, to achieve continuous alignment with humanity's evolving values. Intrinsic proactive superalignment is rooted in a profound understanding of the self, others, and society, integrating self-awareness, self-reflection, and empathy to spontaneously infer human intentions, distinguishing good from evil and proactively considering human well-being, ultimately attaining human-AI co-alignment through iterative interaction. The integration of externally-driven oversight with intrinsically-driven proactive alignment empowers sustainable symbiotic societies through human-AI co-alignment, paving the way for achieving safe and beneficial AGI and ASI for good, for human, and for a symbiotic ecology.