Large Language Models (LLMs) have empowered autonomous agents to handle complex web navigation tasks. While recent studies integrate tree search to enhance long-horizon reasoning, applying these algorithms in web navigation faces two critical challenges: sparse valid paths that lead to inefficient exploration, and a noisy context that dilutes accurate state perception. To address this, we introduce Plan-MCTS, a framework that reformulates web navigation by shifting exploration to a semantic Plan Space. By decoupling strategic planning from execution grounding, it transforms sparse action space into a Dense Plan Tree for efficient exploration, and distills noisy contexts into an Abstracted Semantic History for precise state awareness. To ensure efficiency and robustness, Plan-MCTS incorporates a Dual-Gating Reward to strictly validate both physical executability and strategic alignment and Structural Refinement for on-policy repair of failed subplans. Extensive experiments on WebArena demonstrate that Plan-MCTS achieves state-of-the-art performance, surpassing current approaches with higher task effectiveness and search efficiency.