Multimodal large language models (MLLMs) have shown strong potential for autonomous driving, yet existing benchmarks remain largely ego-centric and therefore cannot systematically assess model performance in infrastructure-centric and cooperative driving conditions. In this work, we introduce V2X-QA, a real-world dataset and benchmark for evaluating MLLMs across vehicle-side, infrastructure-side, and cooperative viewpoints. V2X-QA is built around a view-decoupled evaluation protocol that enables controlled comparison under vehicle-only, infrastructure-only, and cooperative driving conditions within a unified multiple-choice question answering (MCQA) framework. The benchmark is organized into a twelve-task taxonomy spanning perception, prediction, and reasoning and planning, and is constructed through expert-verified MCQA annotation to enable fine-grained diagnosis of viewpoint-dependent capabilities. Benchmark results across ten representative state-of-the-art proprietary and open-source models show that viewpoint accessibility substantially affects performance, and infrastructure-side reasoning supports meaningful macroscopic traffic understanding. Results also indicate that cooperative reasoning remains challenging since it requires cross-view alignment and evidence integration rather than simply additional visual input. To address these challenges, we introduce V2X-MoE, a benchmark-aligned baseline with explicit view routing and viewpoint-specific LoRA experts. The strong performance of V2X-MoE further suggests that explicit viewpoint specialization is a promising direction for multi-view reasoning in autonomous driving. Overall, V2X-QA provides a foundation for studying multi-perspective reasoning, reliability, and cooperative physical intelligence in connected autonomous driving. The dataset and V2X-MoE resources are publicly available at: https://github.com/junwei0001/V2X-QA.