Reconfigurable intelligent surfaces (RISs) have emerged as a promising technique to enhance the system spectral efficiency. This letter investigates the ergodic channel capacity (ECC) of an RIS-aided multiple-input multiple-output channel under the assumption that the transmitter-RIS, RIS-receiver, and transmitter-receiver channels contain deterministic line-of-sight paths. Novel expressions are derived to characterize the upper and lower bounds of the ECC. To unveil more system insights, asymptotic analyses are performed to the system ECC in the limit of large signal-to-noise ratio (SNR) and number of reflecting elements (REs). Theoretical analyses suggest that the RIS's deployment can shape the ECC curve by influencing its high-SNR power offset and the ECC can get improved by increasing the number of REs.