We introduce VocAlign, a novel source-free domain adaptation framework specifically designed for VLMs in open-vocabulary semantic segmentation. Our method adopts a student-teacher paradigm enhanced with a vocabulary alignment strategy, which improves pseudo-label generation by incorporating additional class concepts. To ensure efficiency, we use Low-Rank Adaptation (LoRA) to fine-tune the model, preserving its original capabilities while minimizing computational overhead. In addition, we propose a Top-K class selection mechanism for the student model, which significantly reduces memory requirements while further improving adaptation performance. Our approach achieves a notable 6.11 mIoU improvement on the CityScapes dataset and demonstrates superior performance on zero-shot segmentation benchmarks, setting a new standard for source-free adaptation in the open-vocabulary setting.