SpO$_2$ Predictor-Guided Stage-Wise Time-Frequency Reconstruction of Low-Quality Dual-Wavelength PPG for Oxygen Saturation Estimation

Continuous oxygen saturation (SpO$_2$) estimation from wearable photoplethysmography (PPG) is important for long-term health monitoring, but low-quality red and infrared PPG segments can distort waveform morphology and degrade SpO$_2$ prediction accuracy. Existing PPG denoising and reconstruction methods usually optimize waveform fidelity or heart rate characteristics, while time-domain waveform loss on PPG signals alone insufficiently preserves frequency structure and SpO$_2$-relevant information. This paper proposes a SpO$_2$ predictor-guided stage-wise time-frequency reconstruction framework for low-quality dual-wavelength PPG signals. The proposed method first selects high-quality PPG segments to pretrain a SpO$_2$ predictor. A masked reconstruction model is then trained to recover randomly masked PPG regions using a joint reconstruction objective that combines time-domain waveform loss with frequency-domain loss computed from the short-time Fourier transform (STFT). To make the reconstruction task physiologically relevant, the pretrained SpO$_2$ predictor is incorporated as an additional constraint, encouraging the reconstructed PPG to preserve SpO$_2$ information rather than only minimizing waveform reconstruction error. The SpO$_2$ predictor and PPG reconstructor model are optimized through four training stages. Experiments on the public OpenOximetry Repository and a private wearable PPG dataset show that the proposed approach achieves the lowest subject-level MAE, with 2.882\% on the public dataset and 2.359\% on the private dataset.

Machine Learning Reviews Composition Dependent Thermal Stability in Halide Perovskites

Halide perovskites exhibit unpredictable properties in response to environmental stressors, due to several composition-dependent degradation mechanisms. In this work, we apply data visualization and machine learning (ML) techniques to reveal unexpected correlations between composition, temperature, and material properties while using high throughput, in situ environmental photoluminescence (PL) experiments. Correlation heatmaps show the strong influence of Cs content on film degradation, and dimensionality reduction visualization methods uncover clear composition-based data clusters. An extreme gradient boosting algorithm (XGBoost) effectively forecasts PL features for ten perovskite films with both composition-agnostic (>85% accuracy) and composition-dependent (>75% accuracy) model approaches, while elucidating the relative feature importance of composition (up to 99%). This model validates a previously unseen anti-correlation between Cs content and material thermal stability. Our ML-based framework can be expanded to any perovskite family, significantly reducing the analysis time currently employed to identify stable options for photovoltaics.