Mobile robotic gas distribution mapping (GDM) provides critical situational awareness during emergency responses to hazardous gas releases. However, most systems still rely on teleoperation, limiting scalability and response speed. Autonomous active GDM is challenging in unknown and cluttered environments, because the robot must simultaneously explore traversable space, map the environment, and infer the gas distribution belief from sparse chemical measurements. We address this by formulating active GDM as a next-best-trajectory informative path planning (IPP) problem and propose XIT (Exploration-Exploitation Informed Trees), a sampling-based planner that balances exploration and exploitation by generating concurrent trajectories toward exploration-rich goals while collecting informative gas measurements en route. XIT draws batches of samples from an Upper Confidence Bound (UCB) information field derived from the current gas posterior and expands trees using a cost that trades off travel effort against gas concentration and uncertainty. To enable plume-aware exploration, we introduce the gas frontier concept, defined as unobserved regions adjacent to high gas concentrations, and propose the Wavefront Gas Frontier Detection (WGFD) algorithm for their identification. High-fidelity simulations and real-world experiments demonstrate the benefits of XIT in terms of GDM quality and efficiency. Although developed for active GDM, XIT is readily applicable to other robotic information-gathering tasks in unknown environments that face the exploration and exploitation trade-off.