Liquid crystal (LC) is a promising hardware solution for implementing large RISs, as it is cost-effective, energy efficient, scalable, and capable of providing continuous phase shifts with low power consumption. However, the phase shift response of LC-based RISs is inherently frequency dependent. If unaddressed, this characteristic leads to performance degradation, particularly in wideband scenarios. This issue is especially critical in secure communication applications, where minor phase shift variations across elements can result in considerable information leakage. This paper addresses these frequency-induced variations by developing a physics-based model for an LC unit cell across varying frequencies and proposing a novel phase shift design framework that maximizes secure communication across all subcarriers. Given the large number of elements in millimeter wave (mmWave) LC-RISs, acquiring full channel state information (CSI) is often impractical. Therefore, we optimize the phase shifts based solely on the locations of the legitimate mobile users (MUs) and potential eavesdroppers. Rather than targeting a single user point, the RIS is designed to illuminate a broader area. This approach enhances communication reliability for the MUs and mitigates performance degradation caused by location estimation errors. To solve the problem, we introduce both a semi-definite programming (SDP)-based solution and a low complexity heuristic method. While the SDP-based approach yields superior performance, it incurs higher computational complexity. Conversely, the scalable method exhibits a much slower scaling of complexity, which makes it highly suitable for extremely large RISs. Simulation results demonstrate that both algorithms improve the secrecy rate compared to baseline methods. Finally, the proposed design is validated through experimental evaluations on an LC RIS setup.