Existing work on value alignment typically characterizes value relations statically, ignoring how interventions - such as prompting, fine-tuning, or preference optimization - reshape the broader value system. We introduce the Value Alignment Tax (VAT), a framework that measures how alignment-induced changes propagate across interconnected values relative to achieved on-target gain. VAT captures the dynamics of value expression under alignment pressure. Using a controlled scenario-action dataset grounded in Schwartz value theory, we collect paired pre-post normative judgments and analyze alignment effects across models, values, and alignment strategies. Our results show that alignment often produces uneven, structured co-movement among values. These effects are invisible under conventional target-only evaluation, revealing systemic, process-level alignment risks and offering new insights into the dynamics of value alignment in LLMs.