In commercial web search, aligning content freshness with user intent remains challenging due to the highly varied lifespans of information. Traditional industrial approaches rely on static time-window filtering, resulting in "one-size-fits-all" rankings where content may be chronologically recent but semantically expired. To address the limitation, we present a novel Large Language Models (LLMs)-based Query-Aware Dynamic Content Expiration Prediction Framework deployed in Baidu search, reformulating timeliness as a dynamic validity inference task. Our framework extracts fine-grained temporal contexts from documents and leverages LLMs to deduce a query-specific "validity horizon"-a semantic boundary defining when information becomes obsolete based on user intent. Integrated with robust hallucination mitigation strategies to ensure reliability, our approach has been evaluated through offline and online A/B testing on live production traffic. Results demonstrate significant improvements in search freshness and user experience metrics, validating the effectiveness of LLM-driven reasoning for solving semantic expiration at an industrial scale.