Visualizations are crucial for data communication, yet understanding them requires comprehension of both visual elements and their underlying data relationships. Current multimodal large models, while effective in natural image understanding, struggle with visualization due to their inability to decode the data-to-visual mapping rules and extract structured information. To address these challenges, we present a novel dataset and train multimodal visualization LLMs specifically designed for understanding. Our approach combines chart images with their corresponding vectorized representations, encoding schemes, and data features. The proposed vector format enables compact and accurate reconstruction of visualization content. Experimental results demonstrate significant improvements in both data extraction accuracy and chart reconstruction quality.