In recent years, the field of vision-language model pre-training has experienced rapid advancements, driven primarily by the continuous enhancement of textual capabilities in large language models. However, existing training paradigms for multimodal large language models heavily rely on high-quality image-text pairs. As models and data scales grow exponentially, the availability of such meticulously curated data has become increasingly scarce and saturated, thereby severely limiting further advancements in this domain. This study investigates scalable caption generation techniques for vision-language model pre-training and demonstrates that large-scale low-hallucination synthetic captions can serve dual purposes: 1) acting as a viable alternative to real-world data for pre-training paradigms and 2) achieving superior performance enhancement when integrated into vision-language models through empirical validation. This paper presents three key contributions: 1) a novel pipeline for generating high-quality, low-hallucination, and knowledge-rich synthetic captions. Our continuous DPO methodology yields remarkable results in reducing hallucinations. Specifically, the non-hallucination caption rate on a held-out test set increases from 48.2% to 77.9% for a 7B-size model. 2) Comprehensive empirical validation reveals that our synthetic captions confer superior pre-training advantages over their counterparts. Across 35 vision language tasks, the model trained with our data achieves a significant performance gain of at least 6.2% compared to alt-text pairs and other previous work. Meanwhile, it also offers considerable support in the text-to-image domain. With our dataset, the FID score is reduced by 17.1 on a real-world validation benchmark and 13.3 on the MSCOCO validation benchmark. 3) We will release Hunyuan-Recap100M, a low-hallucination and knowledge-intensive synthetic caption dataset.