Large language models (LLMs) based AI systems increasingly mediate what billions of people see, choose and buy. This creates an urgent need to quantify the systemic risks of LLM-driven market intermediation, including its implications for market fairness, competition, and the diversity of information exposure. This paper introduces ChoiceEval, a reproducible framework for auditing preferences for brands and cultures in large language models (LLMs) under realistic usage conditions. ChoiceEval addresses two core technical challenges: (i) generating realistic, persona-diverse evaluation queries and (ii) converting free-form outputs into comparable choice sets and quantitative preference metrics. For a given topic (e.g. running shoes, hotel chains, travel destinations), the framework segments users into psychographic profiles (e.g., budget-conscious, wellness-focused, convenience), and then derives diverse prompts that reflect real-world advice-seeking and decision-making behaviour. LLM responses are converted into normalised top-k choice sets. Preference and geographic bias are then quantified using comparable metrics across topics and personas. Thus, ChoiceEval provides a scalable audit pipeline for researchers, platforms, and regulators, linking model behaviour to real-world economic outcomes. Applied to Gemini, GPT, and DeepSeek across 10 topics spanning commerce and culture and more than 2,000 questions, ChoiceEval reveals consistent preferences: U.S.-developed models Gemini and GPT show marked favouritism toward American entities, while China-developed DeepSeek exhibits more balanced yet still detectable geographic preferences. These patterns persist across user personas, suggesting systematic rather than incidental effects.