Low Earth Orbit (LEO) satellite networks are integral to next-generation communication systems, providing global coverage, low latency, and minimal signal loss. However, their unique characteristics, such as constrained onboard resources, Line-of-Sight (LoS) propagation, and vulnerability to eavesdropping over wide coverage areas, present significant challenges to physical layer security. To address these challenges, this paper focuses on the design of anti-intercept waveforms for satellite-ground links within Orthogonal Frequency Division Multiplexing (OFDM) systems, aiming to enhance security against eavesdropping threats. We formulate a secrecy rate maximization problem that aims to balance secrecy performance and communication reliability under eavesdropping constraints and sub-carrier power limitations. To solve this non-convex optimization problem, we propose a bisection search-activated neural network (BSA-Net) that integrates unsupervised learning for secure coding optimization and bisection search for dynamic power allocation. The proposed method is structured in two stages: the first optimizes secure coding under power constraints, while the second allocates power across sub-carriers under eavesdropping constraints. Extensive simulation results demonstrate the efficacy of our approach, showcasing significant improvements in secrecy rate performance.