The adaptation of large-scale Vision-Language Models (VLMs) through post-training reveals a pronounced generalization gap: models fine-tuned with Reinforcement Learning (RL) consistently achieve superior out-of-distribution (OOD) performance compared to those trained with Supervised Fine-Tuning (SFT). This paper posits a data-centric explanation for this phenomenon, contending that RL's generalization advantage arises from an implicit data filtering mechanism that inherently prioritizes medium-difficulty training samples. To test this hypothesis, we systematically evaluate the OOD generalization of SFT models across training datasets of varying difficulty levels. Our results confirm that data difficulty is a critical factor, revealing that training on hard samples significantly degrades OOD performance. Motivated by this finding, we introduce Difficulty-Curated SFT (DC-SFT), a straightforward method that explicitly filters the training set based on sample difficulty. Experiments show that DC-SFT not only substantially enhances OOD generalization over standard SFT, but also surpasses the performance of RL-based training, all while providing greater stability and computational efficiency. This work offers a data-centric account of the OOD generalization gap in VLMs and establishes a more efficient pathway to achieving robust generalization. Code is available at https://github.com/byyx666/DC-SFT.