LLM agents require retrieval to behave less like one-shot context fetching and more like reasoning: searching, reading, traversing, and deciding when evidence is sufficient. Yet current Retrieval-Augmented Generation (RAG) systems organize external knowledge as flat chunks retrieved by embedding similarity, exposing a retrieval-as-lookup interface ill-suited to iterative reasoning agents. We propose LLM-Wiki, an agent-native retrieval system that operationalizes the Retrieval-as-Reasoning paradigm by treating external knowledge as a compilable, composable, and self-evolving structure rather than a static retrieval index. LLM-Wiki compiles documents into structured Wiki pages with bidirectional links, exposes search, read, and link-following operations through standard tool-calling interfaces, and introduces an Error Book for persistent structural and semantic self-correction. LLM-Wiki achieves state-of-the-art results on HotpotQA, MuSiQue, and 2WikiMultiHopQA, outperforming HippoRAG 2, LightRAG, and GraphRAG by 2.0-8.1 F1 points. On AuthTrace, LLM-Wiki achieves the best overall accuracy, with especially strong gains on multi-document structured queries, confirming that compilation-based retrieval generalizes beyond chain-style multi-hop reasoning.