Facial expression recognition (FER) is crucial for social interaction in mixed reality environments that employ head-mounted displays (HMD). However, collecting FER data from head-mounted cameras (HMC) is challenging due to privacy concerns and the diversity of HMD platforms. Moreover, existing FER datasets are not directly applicable due to the unique perspectives of HMCs. The lack of sufficient data hinders the development of neural network-based HMC FER methods. To address data scarcity, we propose a data synthesis framework that generates HMC-view images from frontal-view images, leveraging abundant existing annotated datasets. Specifically, we first reconstruct 3D textured meshes from images and then apply a configurable camera system to render images from the HMC perspective. Additionally, we introduce a texture-space alignment network (TSAN) that enables accurate texture sampling from images to preserve detailed facial expressions. To evaluate the proposed method, we conduct extensive experiments on both simulated and real HMC datasets. Experimental results demonstrate that models trained on our synthetic dataset outperform those trained on existing datasets and exhibit better generalization across different camera configurations.