We present a novel multicarrier waveform, termed chirp-permuted affine frequency division multiplexing (CP-AFDM), which introduces a unique chirp-permutation domain on top of the chirp subcarriers of the conventional AFDM. Rigorous analysis of the signal model and waveform properties, supported by numerical simulations, demonstrates that the proposed CP-AFDM preserves all core characteristics of affine frequency division multiplexing (AFDM) - including robustness to doubly-dispersive channels, peak-to-average power ratio (PAPR), and full delay-Doppler representation - while further enhancing ambiguity function resolution and peak-to-sidelobe ratio (PSLR) in the Doppler domain. These improvements establish CP-AFDM as a highly attractive candidate for emerging sixth generation (6G) use cases demanding both reliability and sensing-awareness. Moreover, by exploiting the vast degree of freedom in the chirp-permutation domain, two exemplary multifunctional applications are introduced: an index modulation (IM) technique over the permutation domain which achieves significant spectral efficiency gains, and a physical-layer security scheme that ensures practically perfect security through permutation-based keying, without requiring additional transmit energy or signaling overhead.