Traditional models for pricing catastrophe (CAT) bonds struggle to capture the complex, relational data inherent in these instruments. This paper introduces CATNet, a novel framework that applies a geometric deep learning architecture, the Relational Graph Convolutional Network (R-GCN), to model the CAT bond primary market as a graph, leveraging its underlying network structure for spread prediction. Our analysis reveals that the CAT bond market exhibits the characteristics of a scale-free network, a structure dominated by a few highly connected and influential hubs. CATNet demonstrates high predictive performance, significantly outperforming a strong Random Forest benchmark. The inclusion of topological centrality measures as features provides a further, significant boost in accuracy. Interpretability analysis confirms that these network features are not mere statistical artifacts; they are quantitative proxies for long-held industry intuition regarding issuer reputation, underwriter influence, and peril concentration. This research provides evidence that network connectivity is a key determinant of price, offering a new paradigm for risk assessment and proving that graph-based models can deliver both state-of-the-art accuracy and deeper, quantifiable market insights.