Decentralized Federated Learning (DFL) remains highly vulnerable to adaptive backdoor attacks designed to bypass traditional passive defense metrics. To address this limitation, we shift the defensive paradigm toward a novel active, interventional auditing framework. First, we establish a dynamical model to characterize the spatiotemporal diffusion of adversarial updates across complex graph topologies. Second, we introduce a suite of proactive auditing metrics, stochastic entropy anomaly, randomized smoothing Kullback-Leibler divergence, and activation kurtosis. These metrics utilize private probes to stress-test local models, effectively exposing latent backdoors that remain invisible to conventional static detection. Furthermore, we implement a topology-aware defense placement strategy to maximize global aggregation resilience. We provide theoretical property for the system's convergence under co-evolving attack and defense dynamics. Numeric empirical evaluations across diverse architectures demonstrate that our active framework is highly competitive with state-of-the-art defenses in mitigating stealthy, adaptive backdoors while preserving primary task utility.