Diffusion and flow-matching samplers integrate a learned probability-flow ODE from a large noise scale down to a small terminal floor $σ_{\min}$, at which the score is stiff and the flow develops a boundary layer. We treat $σ_{\min}$ as a singular-perturbation parameter and determine which fixed-step samplers are asymptotic-preserving (AP), that is, stable and uniformly accurate as $σ_{\min}\to0$, casting the criteria as an a posteriori audit: residual functionals with $σ_{\min}$-uniform coefficients, computable on a pretrained checkpoint without ground-truth scores or exact trajectories. On the terminal layer, Euler in the $σ$-clock, the deterministic DDIM update, is the unique layer-exact discretization up to affine reparameterization, with rectified flow its flow-matching counterpart; the $λ$-clock is stable only for steps $h\le h_\star=1+W(1/e)$, and the uniform-$σ^2$ heat clock stalls a $σ_{\min}$-independent distance from the data. On two solvable models (rank-deficient Gaussian, symmetric two-point mixture), deterministic samplers remain first-order uniformly accurate with no $\log(1/σ_{\min})$ factor, even across a symmetric posterior-switching interface whose distributional budget is a universal constant; the logarithm is charged entirely to the Itô term of stochastic samplers, whose path-KL scales as $Λ^2/N$ against the ODE's $O(Λ^2/N^2)$ budget, with $Λ=\log(σ_{\max}/σ_{\min})$. On the EDM CIFAR-10 checkpoint, spectra measured once predict held-out residual budgets across step count, schedule, and noise level against pre-specified gates with no per-configuration refitting, and calibrate the Itô coefficient at $M_1=1.00\pm0.01$. The clock decides stability; the noise, not the geometry, charges the logarithm.