Unlike their conventional use as estimators of probability density functions in reinforcement learning (RL), this paper introduces a novel function-approximation role for Gaussian mixture models (GMMs) as direct surrogates for Q-function losses. These parametric models, termed GMM-QFs, possess substantial representational capacity, as they are shown to be universal approximators over a broad class of functions. They are further embedded within Bellman residuals, where their learnable parameters -- a fixed number of mixing weights, together with Gaussian mean vectors and covariance matrices -- are inferred from data via optimization on a Riemannian manifold. This geometric perspective on the parameter space naturally incorporates Riemannian optimization into the policy-evaluation step of standard policy-iteration frameworks. Rigorous theoretical results are established, and supporting numerical tests show that, even without access to experience data, GMM-QFs deliver competitive performance and, in some cases, outperform state-of-the-art approaches across a range of benchmark RL tasks, all while maintaining a significantly smaller computational footprint than deep-learning methods that rely on experience data.