Do Language Models Know When They'll Refuse? Probing Introspective Awareness of Safety Boundaries

Large language models are trained to refuse harmful requests, but can they accurately predict when they will refuse before responding? We investigate this question through a systematic study where models first predict their refusal behavior, then respond in a fresh context. Across 3754 datapoints spanning 300 requests, we evaluate four frontier models: Claude Sonnet 4, Claude Sonnet 4.5, GPT-5.2, and Llama 3.1 405B. Using signal detection theory (SDT), we find that all models exhibit high introspective sensitivity (d' = 2.4-3.5), but sensitivity drops substantially at safety boundaries. We observe generational improvement within Claude (Sonnet 4.5: 95.7 percent accuracy vs Sonnet 4: 93.0 percent), while GPT-5.2 shows lower accuracy (88.9 percent) with more variable behavior. Llama 405B achieves high sensitivity but exhibits strong refusal bias and poor calibration, resulting in lower overall accuracy (80.0 percent). Topic-wise analysis reveals weapons-related queries are consistently hardest for introspection. Critically, confidence scores provide actionable signal: restricting to high-confidence predictions yields 98.3 percent accuracy for well-calibrated models, enabling practical confidence-based routing for safety-critical deployments.