This paper presents a modified model predictive control (MPC) framework for real-time power system operation. The framework incorporates a diffusion model tailored for time series generation to enhance the accuracy of the load forecasting module used in the system operation. In the absence of explicit state transition law, a model-identification procedure is leveraged to derive the system dynamics, thereby eliminating a barrier when applying MPC to a renewables-dominated power system. Case study results on an industry park system and the IEEE 30-bus system demonstrate that using the diffusion model to augment the training dataset significantly improves load-forecasting accuracy, and the inferred system dynamics are applicable to the real-time grid operation with solar and wind.